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World 1 · Atoms & Bonds · 6 min

Polar molecules

When sharing isn’t equal

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Not all atoms pull on shared electrons equally. An atom’s greed for electrons is its electronegativity. When a bond links two atoms of different electronegativity, the electrons sit closer to the greedier one, giving it a slight negative charge and its partner a slight positive charge — a polar bond.

Whether the whole molecule is polar depends on its shape. Water is bent, so its two polar O–H bonds don’t cancel — water is strongly polar, which is why it dissolves so much. Carbon dioxide has polar bonds too, but its linear shape makes them cancel, so CO₂ is non-polar overall.

Check yourself

Water is a polar molecule mainly because…

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