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World 1 · Structure & Bonding · 8 min

sp³, sp² and sp

Shape follows from how many things are attached

Teaching this? Open projector mode

Count what is attached to a carbon — bonded atoms plus lone pairs. That count, the steric number, fixes the shape:

  • 4 → sp³, tetrahedral, 109.5°
  • 3 → sp², trigonal planar, 120°
  • 2 → sp, linear, 180°

The electrons repel each other and end up as far apart as possible. That is the whole derivation.

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A double bond counts as one thing for shape purposes, not two: the two carbons of ethene each have three attachments, so each is trigonal planar. The second bond of the pair (the π bond) sits above and below that plane rather than adding another direction.

This is why ethene is flat and cannot twist — twisting would break the π overlap — while ethane spins freely. That single difference is the subject of the whole conformation unit.

Check yourself

The carbon of a C=O group in acetone has how many attachments, and what shape?

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